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Cyclohexanone

Cyclohexanone (also known as oxocyclohexane, pimelic ketone, ketohexamethylene, cyclohexyl ketone or ketocyclohexane) is a six-carbon cyclic molecule with a ketone functional group. It is a colorless, oily liquid with an acetone-like smell. Cyclohexanone appears as a colorless to pale yellow liquid with a pleasant odor. Less dense than water. Flash point 111 °F. Vapors heavier than air. Used to make nylon, as a chemical reaction medium, and as a solvent. Cyclohexanone is a cyclic ketone that consists of cyclohexane bearing a single oxo substituent. It has a role as a human xenobiotic metabolite.

  • CAS #: 108-94-1
  • Purity: >99%, 99%, 98% and 90%
  • Packaging Details: 195 kg (200 litres) Drum
  • Synonyms: Ketohexamethylene, Pimelic ketone, Sextone
  • EC Number: 203-631-1
  • Molar Mass: 98.14 g/mol
  • Hill Formula: C₆H₁₀O
SKU: JY2301081527 Category: Tags: ,

Description

Cyclohexanone

Cyclohexanone is a toxic, flammable, cyclic, six-carbon organic molecule with a ketone functional group. Applications for the compound include use in the production of nylon, as a chemical reaction medium, and as a solvent. Cyclohexanone is used as a solvent for photoresist, an edge bead remover, and a general solvent for organic polymers resists.

Cyclohexanone (also known as ketohexamethylene, pimelic ketone, sextone, cyclohexyl ketone, nadone, anone, anon, cyclohexanon or hexanon), is an organic compound with the formula C6H10O and CAS No. 108-94-1. Structurally, it is a cyclic, six-carbon ketone derived from cyclohexane, with the addition of a single oxo functional group. It is a clear, colorless-to-pale-yellow, oily liquid that has limited miscibility with water. However, it is highly miscible with a range of other organic solvents such as acetone, ether, or alcohol. It has a slightly peppermint, acetone-like odor. Physical data: boiling point 155°C; density 0.947g/cm³; melting point −47.0°C.

Cyclohexanone, 99+%
CAS number: 108-94-1
MDL number: MFCD00001625
Molecular formula: C6H10O
Molecular weight: 98.15
Product Specification
Appearance (Color): Clear colorless
Form: Liquid
Assay (GC): ≥99.0%
Identification (FTIR): Conforms
Water Content (Karl Fischer Titration): ≤0.5%
Refractive Index: 1.4495-1.4520 @ 20°C
Date of Print: January 7, 2023
Version: 7
Product Specifications are subject to amendment and may change over time.

Cyclohexanone Uses in Industrial Chemistry
• As a stock chemical for the manufacture of nylon (via conversion to adipic acid)
• As an intermediate in the synthesis of industrial products, especially pharmaceuticals, herbicides, insecticides, dyes, rubbers, and plasticizers
• As an industrial solvent for resins, waxes, fats, and cellulose lacquers
• As a metal degreasing solvent or cleaner
• As a precursor for organic synthesis, and sometimes as a solvent, in the research laboratory

This product is available in a range of purity grades depending on the application, for example, ‘extra pure’ or ‘suitable for analysis’.

Cyclohexanone is a corrosive, highly flammable liquid, and is harmful if inhaled. Storage in a cool, secure location is therefore recommended. When using this product, the information and advice given in the Safety Data Sheet should be observed. Due attention should also be given to the appropriate precautions necessary for handling chemicals.

Cyclohexanone, 99+%

MDL: MFCD00001625
EINECS: 203-631-1

Chemical Properties

Formula: C6H10O
Formula Weight: 98.15
Melting point: -26°
Boiling Point: 154-156°
Flash Point: 47°(116°F)
Density: 0.948
Refractive Index: 1.4507
Storage & Sensitivity: Ambient temperatures.
Solubility: Miscible with diethyl ether, acetone and alcohol. Slightly miscible with water.

Applications

Cyclohexanone is used in the preparation of synthetic polymer such as nylon 6,6 and nylon 6. It acts as a solvent in organic synthesis. Its derivatives are used for the synthesis of dyes, rubber chemicals, plasticizers and pharmaceuticals. Further, it is involved in the preparation of cyclohexanone oxime, which rearranges to give caprolactam in the presence of sulfuric acid catalyst.

Notes

Incompatible with strong oxidizing agents, red metals, lead, amines, sulfuric acid, nitric acid, strong acids, aliphatic amines, rubber, resins and alkalies.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302+H312+H332-H315-H318-H335-H336

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P314-P330-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant.

Other References

Merck: 14,2726
Beilstein: 385735
Hazard Class: 3
Packing Group: III
Harmonized Tariff Code: 2914.22
TSCA: Yes
RTECS: GW1050000

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