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Propionic acid

Propionic Acid is an organic acid that naturally occars in the rumen, its purpose is to inhibit moulds, yeast and bacteria. Propionic acid is a linear monocarboxylic acid. It affords esters on reaction with alcohols or alkenes. It can be synthesized by reacting ethane, carbon monoxide and water. It participates as a precursor in the preparation of smallest azolium homoenolate intermediate. Propionic acid may be used in the synthesis of cellulose propionate (cellulose ester).

  • Synonym(s): Acid C3, Propanoic acid, Propanyl acid
  • Linear Formula: CH3CH2COOH
  • CAS Number: 79-09-4
  • EC Number: 201-176-3
  • MDL Number: MFCD00002756
  • Assay:  ≥99.5% (GC)
  • Packaging Type: 210KG/Drum
SKU: JY2301252128 Category: Tags: , Manufacturer and Supplier: Subsidiary of Junyuan Petroleum Group -

Description

Propionic Acid has one carboxylic group. It is a colorless liquid. Propionic acid is used in feed and food for preservation as free acid or as sodium/calcium salts. In these applications the Propionic Acid is active as a powerful Mould Inhibitor. Other areas are ester solvents, pharmaceutical intermediates, herbicides, synthetic flavors and fragrances.

Packaging options

  • Drum
  • IBC
  • Bulk

Chemical Formula : 

C3H6O2

Propionic Acid

CAS Number: 79-09-4
HS Number: 291550
Formula Weight: 74.08
Formula: CH3CH2COOH
Hazard Info: Flammable, Corrosive
Density (g/mL): 0.9950
Boiling Point (°C): 140.8
Freezing Point (°C): -20.7
Solubility: Water, Alcohol, and Chloroform
Synonyms: Propanoic Acid
Shelf Life (months): 36
Storage: White

Note: The chemical specifications for some items on this product page may differ from the specifications listed above. For more information, consult the Safety Data Sheet or contact your Junyuan Petroleum Group’s sales representative.

Delivery information: This product is designed for educational and teaching laboratories, and no certificate of analysis is available.

Propionic acid

Propionic acid is a water-soluble organic acid serving a range of applications. Propionic acid is used as a versatile preservative in food or feed industry. For bakery products it preserves as a proprionate. In animal feed applications, propionic acid preserves compound feed, grain or corn while reducing mold or yeast. In silage applications it improves fermentation. It also serves as a synthetic building block to produce pharmaceuticals, crop protection agents and solvents, as well as thermoplastics.

Product Number JY2301252128
Purity / Analysis Method >99.0%(GC)(T)
Molecular Formula / Molecular Weight C3H6O2 = 74.08
Physical State (20 deg.C) Liquid
CAS RN 79-09-4
Reaxys Registry Number 506071
PubChem Substance ID /
SDBS (AIST Spectral DB) 1033
Merck Index (14) 7825
MDL Number MFCD00002756
Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 99.0 %
Purity(Neutralization titration) min. 99.0 %
Properties (reference)
Boiling Point 140 °C
Flash point 52 °C
Specific Gravity (20/20) 1.00
Refractive Index 1.39
Solubility in water Completely miscible
Solubility (soluble in) Alcohol,Ether
GHS
Pictogram   
Signal Word Danger
Hazard Statements H311 : Toxic in contact with skin.
H314 : Causes severe skin burns and eye damage.
H335 : May cause respiratory irritation.
H412 : Harmful to aquatic life with long lasting effects.
H226 : Flammable liquid and vapor.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P273 : Avoid release to the environment.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P234 : Keep only in original container.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P390 : Absorb spillage to prevent material damage.
P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
RTECS# UE5950000
Transport Information:
UN Number UN3463
Class 8 / 3
Packing Group II

Packaging
0,5KG, 1KG Glass bottle
190KG, 200KG Plastic drums
950KG Composite IBC
Bulk

Propionic acid, 99%

MDL: MFCD00002756
EINECS: 201-176-3

Chemical Properties

Formula: C3H6O2
Formula Weight: 74.08
Melting point: -21°
Boiling Point: 140-141°
Flash Point: 51°(123°F)
Density: 0.992
Refractive Index: 1.3875
Storage & Sensitivity: Ambient temperatures.
Solubility: Miscible with water, alcohol, diethyl ether and chloroform.

Applications

Propionic acid is used as a preservative for animal feed and food for human consumption. It acts as an intermediate in the production of polymers like cellulose-acetate-propionate, artificial flavorings, agrochemicals and in bleaching agents. In addition, it is used in the synthesis of morphans.

Notes

Incompatible with strong oxidizing agents.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H290-H314-H335

Flammable liquid and vapour. May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P234-P240-P241-P242-P243-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P362+P364-P390-P402-P403+P233-P406b-P501c

Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep only in original container. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. And wash it before reuse. Absorb spillage to prevent material damage. Store in a dry place. Store in a well-ventilated place. Keep container tightly closed. Store in corrosive resistant polypropylene container with a resistant inliner Dispose of contents/ container to an approved waste disposal plant

Other References

Merck: 14,7825
Beilstein: 506071
Hazard Class: 8
Packing Group: II
Harmonized Tariff Code: 2915.50
TSCA: Yes
RTECS: UE5950000

Chemical Identifiers

CAS: 79-09-4
IUPAC Name: propanoic acid
Molecular Formula: C3H6O2
InChI Key: XBDQKXXYIPTUBI-UHFFFAOYSA-N
SMILES: CCC(O)=O
Molecular Weight (g/mol): 74.08
Synonym: propanoic acid toxi-check caswell no. 707 propcorn propkorn fema number 2924 pseudoacetic acid C3 acid metacetonic acid kyselina propionova
Appearance (Form): Clear liquid
Color scale: =<10 APHA
Infrared spectrum: Conforms
GC: >=98.5 %
Water: =<0.2 %
Refractive index: 1.3850 to 1.3870 (20°C, 589 nm)
assay ≥99.5% (GC)
autoignition temp. 955 °F
bp 141 °C (lit.)
cation traces Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.1 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.5 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤1 mg/kg
Ni: ≤0.1 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg
density 0.993 g/mL at 25 °C (lit.)
expl. lim. 12.1 %
form liquid
grade puriss. p.a.
InChI 1S/C3H6O2/c1-2-3(4)5/h2H2,1H3,(H,4,5)
InChI key XBDQKXXYIPTUBI-UHFFFAOYSA-N
mp −24-−23 °C (lit.)
Quality Level 200
refractive index n20/D 1.386
n20/D 1.386 (lit.)
SMILES string CCC(O)=O
solubility organic solvents: soluble(lit.)
water: soluble(lit.)
vapor density 2.55 (vs air)
vapor pressure 2.4 mmHg ( 20 °C)
Symbol   GHS02,GHS05,GHS07
Signal word Danger
Hazard statements H226 – H314 – H335
Precautionary statements P210 – P233 – P240 – P280 – P303 + P361 + P353 – P305 + P351 + P338
Hazard Codes C
Risk Statements 10-34-37
Safety Statements 23-36-45
RIDADR UN3463 – class 3 – Propionic acid
WGK Germany WGK 1
Flash Point(F) 129.2 °F – closed cup
Flash Point(C) 54 °C – closed cup
Purity ≥99.5% (GC)
bp 141 °C (lit.)
mp −24-−23 °C (lit.)
Density 0.993 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.386 (lit.); n20/D 1.386
UNSPSC 12352100

 

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