Sodium Methoxide 30% Solution in Methanol, CAS No.124-41-4
Sodium Methoxide, 30% w/w Solution in Methanol
CAS No. 124-41-4, EC Number 204-699-5
Appearance: milky white to colorless transparent liquid
Miscibility: Miscible with Methanol
Assy % (w/w): 29.00 – 31.00
NAOH & NA2CO3AS H2O (Free Alkali)*: 0.20% Max.
NAOH & NA2CO3AS NAOH (Free Alkali): 0.44% Max.
* Free water below 1000 PPM.
Storage Conditions: sealed storage, ventilated warehouse, low temperature and dry. Keep away from kindling and heat sources. It shall be stored and transported separately from oxidants and acids.
Packing: 200 kg / drum
Description
Description:
Synonyms: Sodium Methylate
CAS Number: 124-41-4
Formula: CH3NaO
Formula Weight: 54.02
Linear Formula: CH3ONa
MDL No.: MFCD00012179
Density: 0.945 g/mL at 25 C
Refractive Index: n20/D 1.37
Beilstein Registry Number: 3592982
UNSPSC Code: 12352100
General description: The product is 30wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.
Application: A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.
Application: Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP). Liquid sodium methoxide is widely used in the production of sulfonamides. Sodium methoxide is also a metal catalyst for organic synthesis, which is used in the production and processing of chemical fertilizer and vegetable oil.
There are two ways of sodium methoxide commodity in industrial production: solid and liquid. The solid is pure sodium methoxide and the liquid is methanol solution of sodium methoxide. The content of sodium methoxide is 27.5 ~ 31%.
Because sodium methoxide is a hazardous chemical, it is inseparable and closed when packaging. Be sure to ensure safety.
General plastics, such as PP, ABS and PC, are all etched by ethanol. Only PTFE plastics can be used, but the price is very high. It is proposed to use steel drums.
Specification
RIDADR: UN1289 – class 3 – PG 2 – Sodium Methylate Solutions
Flash Point(F): 51.8 F
Flash Point(C): 11 C
R Codes: 11-14-23/24/25-34-39/23/24/25
S Codes: 16-26-36/37/39-45
IOD Codes: F,T
Symbol: GHS02, GHS05, GHS06, GHS08
Signal Word: Danger
Hazard Statements: H225-H251-H301 + H311 + H331-H314-H370
Precautionary statements: P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338
